Kinetic analysis of Cr(VI) transport with electromembrane processes

Calik G., Kaya A., ONAÇ C., AYTAÇ A., ALPOĞUZ H. K.

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, cilt.97, sa.3, ss.662-667, 2022 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 97 Sayı: 3
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1002/jctb.6948
  • Dergi Adı: JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aerospace Database, Agricultural & Environmental Science Database, Applied Science & Technology Source, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, Computer & Applied Sciences, EMBASE, Food Science & Technology Abstracts, INSPEC, Metadex, Pollution Abstracts, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.662-667
  • Anahtar Kelimeler: supported liquid membrane, Aliquat 336, Celgrad 2500, electromembrane extraction, POLYMER INCLUSION MEMBRANE, LIQUID-MEMBRANES, EXTRACTION, CHROMIUM, REMOVAL, STABILITY, DAMAGE, IONS
  • Gazi Üniversitesi Adresli: Evet

Özet

BACKGROUND In this study, the transport of Cr (VI) ions was investigated with electroanalytical approach, called electro-membrane extraction (EME), by using a supported liquid membrane (SLM). RESULTS Aliquat 336 and Celgrad 2500 were used as a carrier and support material, respectively. Chromium (VI) ions were transferred from sample solution containing target analyte to extractant solution at low potential values (10-50 V) and with different current values (0.1-0.4 A). CONCLUSION The following parameters such as carrier change, carrier concentration effects, solvent change effect were investigated and Cr(VI) transport was achieved with 54.73% recovery in 100 min at optimum conditions. In the EME-SLM process, Danesi mass transfer model was used to calculate the kinetic data, rate constant, flux, permeability, and recovery, for each parameter examined. (c) 2021 Society of Chemical Industry (SCI).