Synthesis, Characterization, Conductivity and Investigation of Antimicrobial and Fungus of Magnetic Polymer Including Schiff Bases

SARI N., Nartop D., Logoglu E.

ASIAN JOURNAL OF CHEMISTRY, cilt.21, sa.3, ss.2331-2339, 2009 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 21 Sayı: 3
  • Basım Tarihi: 2009
  • Dergi Adı: ASIAN JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2331-2339
  • Anahtar Kelimeler: Schiff bases, Coordination polymer, Magnetic polymer, Poly(acrylamide), ELECTRORHEOLOGICAL PROPERTIES, COMPLEXES, COMPOSITES
  • Gazi Üniversitesi Adresli: Evet

Özet

Novel poly-Schiff base derived from the condensation reaction poly(acrylamide) and 2,2'-bipridine-4,4'-dicarboxaldehyde has been synthesized. -CH=N- and -NH(2) group (1)H NMR signals were made use of to determine the relative abundance of Schiff base and acrylamide groups in the modified polymer. Metal-aldehyde complexes ([Ni-L], [Co-L], [Mn-L], [Fe-L], [Cr-L]) were anchored poly(acrylamide). PAA(m)-Schiff base and its metal complexes were characterized by magnetic susceptibility, electronic and spectral studies. The DC conductivities of the solid samples were measured using a four-probe technique. The conductivity of coordination polymers were found to be high in comparison to PAX, including Schiff bases. In vitro activities against some Gram-positive (Bacillus subtillis, Bacillus cereus, Micrococcus luteus NRLL 134375, Pseudomonas aeroginosa ATCC 29212) and the fungus Candida albicans were determined.