Synthesis of novel C-2 substituted imidazoline derivatives having the norbornene/dibenzobarrelene skeletons

ÇAPAN İ., SERVİ S.

ARKIVOC, pp.131-142, 2018 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Publication Date: 2018
  • Doi Number: 10.24820/ark.5550190.p010.654
  • Journal Name: ARKIVOC
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.131-142
  • Keywords: Cycloadditions, imidazoline, norbornene, dibenzobarrelene, guanidine, amide, ONE-POT SYNTHESIS, FACILE SYNTHESIS, 2-IMIDAZOLINES, BENZIMIDAZOLES, CATALYST, SCAFFOLD, DESIGN, SYSTEM
  • Gazi University Affiliated: Yes

Abstract

Novel imidazoline derivatives were synthesized from the norbornene and dibenzobarrelene skeletons which were obtained by the Diels-Alder reactions of anthracene and cyclopentadiene with the different dienophiles, such as fumaronitrile and fumaric acid. Synthesis of the C-2 substituted imidazolines was performed with high yields from various dinitriles and diacyl dichlorides.