Vibrational spectroscopic investigation of metal[II] tetracyanonickelate complexes of 4-acetylpyridine and acridine

Yurdakul Ş., Gulluoglu M., Kucukguldal D., Tasdelen M.

JOURNAL OF MOLECULAR STRUCTURE, cilt.408, ss.319-324, 1997 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 408
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1016/s0022-2860(96)09675-5
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.319-324
  • Gazi Üniversitesi Adresli: Evet

Özet

Infrared spectra of M(4-apy)(2)Ni(CN)(4) (M = Cd, Co, Fe or Ni; 4-apy = 4-acetylpyridine) and IR and Raman spectra of M(acr)(2)Ni(CN)(4) (M = Mn, Co, Zn, Ni, Cu, or Cd; acr = acridine) complexes are reported. Spectroscopic and magnetic susceptibility measurements indicate that the compounds have the structure of Hofmann-type complexes. The Cu(acr) 2Ni(CN)4 complex has spectral features different from the other compounds. (C) 1997 Elsevier Science B.V.