Synthesis and characterization of a proton transfer salt between dipicolinic acid and 2-amino-6-methylbenzothiazole and its complexes, and their inhibition studies on carbonic anhydrase isoenzymes


İLKİMEN H., YENİKAYA C., SARI M., BÜLBÜL M., TUNCA E., SÜZEN Y.

POLYHEDRON, cilt.61, ss.56-64, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 61
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1016/j.poly.2013.05.040
  • Dergi Adı: POLYHEDRON
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.56-64
  • Anahtar Kelimeler: 2-Amino-6-methylbenzothiazole, Dipicolinic acid, Proton transfer, Inhibition, Carbonic anhydrase, NI-II, SPECTRA, DERIVATIVES, CHEMISTRY, COMPOUND, ESTERASE, BEHAVIOR, CO(II), IRON
  • Gazi Üniversitesi Adresli: Evet

Özet

A novel proton transfer compound (HMeABT)(+)(HDPC)(-)center dot H2O (1) obtained from 2-amino-6-methylbenzothiazole (MeABT) and dipicolinic acid (H2DPC) and its Fe(III), Fe(II), Co(II), Ni(II) and Cu(II) complexes (2-6) have been prepared and characterized by elemental, spectral (H-1 NMR, IR and UV-Vis) and thermal analyses, magnetic measurement and molar conductivity. Additionally, single crystal X-ray diffraction techniques were applied to all complexes.