Infrared spectroscopic study on the Hofmann-dadn-type and the T-d-dahxn-type clathrates

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Ozbay A., Saglam S., Sertbakan T. R., Kasap E., Ozcelik S.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.58, no.1-2, pp.49-54, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 58 Issue: 1-2
  • Publication Date: 2007
  • Doi Number: 10.1007/s10847-006-9109-y
  • Journal Name: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
  • Page Numbers: pp.49-54
  • Keywords: clathrates, infrared spectroscopy, 1,10-diaminodecane, 1,6-diaminohexane, VIBRATIONAL-SPECTRA, CRYSTAL-STRUCTURES, DISUBSTITUTED COMPOUNDS, BENZENE DERIVATIVES, INCLUSION-COMPOUNDS, CD, M=MN, HG, CO, COMPLEXES
  • Gazi University Affiliated: Yes

Abstract

Infrared spectra of M(1,10-diaminodecane)Ni(CN)(4)center dot,1,5 G ( M=Co, Ni or Cd; G=o-xylene, m-xylene, p-xylene) and Cd(1,6-diaminohexane)M(CN)(4)center dot C6H6 ( M=Cd or Hg) clathrates are reported. The 1,10-diaminodecane and 1,6-diaminohexane molecules in the host permit the inclusion of bulky guest molecules. The spectral data of clathrates were compared with those of the corresponding host. The spectral features suggest that these compounds are similar in structure to other Hofmann-type and Hofmann-T-d type clathrates, respectively.