Fourier transform infrared and Raman spectroscopic studies on 8-hydroxyquinoline metal(II) tetracyanonickelate complexes


Yurdakul Ş.

JOURNAL OF MOLECULAR STRUCTURE, vol.412, no.3, pp.231-237, 1997 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 412 Issue: 3
  • Publication Date: 1997
  • Doi Number: 10.1016/s0022-2860(96)09527-0
  • Journal Name: JOURNAL OF MOLECULAR STRUCTURE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.231-237
  • Gazi University Affiliated: Yes

Abstract

The results of an infrared and Raman spectroscopic study are reported for seven new metal(II) 8-hydroxyquinoline tetracyanonickelate complexes, M(8-HQ)(2) Ni(CN)(4) [where (8-HQ) = 8-hydroxyquinoline; M = Mn, Fe, Co, Zn, Ni, Cu or Cd]. Spectroscopic and magnetic susceptibility measurements indicate that the compounds have the structure of Hofmann-type complexes. The copper complex has spectral features different from the other six compounds. (C) 1997 Elsevier Science B.V.