Photophysical and theoretical studies on newly synthesized N,N-diphenylamine based azo dye

Aksungur T., Arslan O., SEFEROĞLU N., SEFEROĞLU Z.

JOURNAL OF MOLECULAR STRUCTURE, cilt.1099, ss.543-550, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1099
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1016/j.molstruc.2015.07.010
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.543-550
  • Anahtar Kelimeler: Diphenylamine based azo dye, UV-Vis, Tautomerism, DFT, Acidochromism, Non-linear optic (NLO), MONOAZO DISPERSE DYES, SPECTRAL PROPERTIES, THERMAL-STABILITY, AZOMETHINE DYES, ORANGE 1, DENSITY, DNA, APPROXIMATION, TAUTOMERISM, MOLECULES
  • Gazi Üniversitesi Adresli: Evet

Özet

The azo-hydrazone tautomerism, solvatochromism and halochromism in diphenylamine based azo dye ((E)-1-(4-((4-(phenylamino)phenyl)diazenyl)phenyl)ethanone, DPA) were examined. The absorption wavelengths of the dye in different solvents were in the range 429-544 nm. The compound exhibits positive solvatochromism as the absorption band is red shifted with increasing solvent polarity. In addition, the absorption properties of the dye change drastically upon acidification, as the protonation of beta-nitrogen atom of the azo group increases the donor-acceptor interplay of the pi system. The experimental results are fully supported by DFT and TD-DFT calculations. Moreover, nonlinear optical properties (NLO) were also obtained by the theoretically predicted values of dipole moment (mu), polarizability (alpha) and first hyperpolarizability (beta). (C) 2015 Elsevier B.V. All rights reserved.