Infrared spectroscopic study of the Hofmann-daon-type clathrates: M(1,8-diaminooctane)Ni(CN)(4)center dot G (M = Co, Ni or Cd; G = Aromatic guest molecules)


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Kasap E., Ozbay A.

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, cilt.28, ss.335-347, 1997 (SCI-Expanded) identifier identifier

Özet

Infrared spectra of M(1,8-diaminooctane)Ni(CN)(4) . G (M=Co, Ni or Cd; G=benzene, chlorobenzene, toluene, p-xylene, naphthalene or biphenyl) compounds are reported. The 1,8-diaminooctane molecules in the host permit the inclusion of bulky guest molecules. The spectral features suggest that the compounds are similar in structure to the Hofmann-type clathrates.