Infrared spectroscopic study of the Hofmann-daon-type clathrates: M(1,8-diaminooctane)Ni(CN)(4)center dot G (M = Co, Ni or Cd; G = Aromatic guest molecules)


Kasap E. , Ozbay A.

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, vol.28, pp.335-347, 1997 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 28
  • Publication Date: 1997
  • Doi Number: 10.1023/a:1007965300424
  • Title of Journal : JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY
  • Page Numbers: pp.335-347

Abstract

Infrared spectra of M(1,8-diaminooctane)Ni(CN)(4) . G (M=Co, Ni or Cd; G=benzene, chlorobenzene, toluene, p-xylene, naphthalene or biphenyl) compounds are reported. The 1,8-diaminooctane molecules in the host permit the inclusion of bulky guest molecules. The spectral features suggest that the compounds are similar in structure to the Hofmann-type clathrates.