Synthesis, characterization, optical and electrochemical performances of 3-fold interpenetrated Copper(II) coordination polymer with a flexible zwitterionic ligand

Ciftci E., ARICI M., Demir E., Demir-Cakan R., Wriedt M., YEŞİLEL O. Z.

JOURNAL OF SOLID STATE CHEMISTRY, cilt.302, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 302
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1016/j.jssc.2021.122375
  • Dergi Adı: JOURNAL OF SOLID STATE CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Chemical Abstracts Core, Chimica, Compendex, INSPEC, Metadex
  • Anahtar Kelimeler: Coordination polymer, 1,1'-([1,1'-biphenyl]-4,40-diylbis(methylene)), bis(3-carboxypyridin-1-ium compound, Zwitterionic compound, Copper(II) compound and Li-Ion battery, METAL-ORGANIC FRAMEWORKS, LI-ION, CRYSTAL-STRUCTURES, ANODE MATERIALS, COMPOSITES, ELECTRODES, CONVERSION, BATTERIES
  • Gazi Üniversitesi Adresli: Evet

Özet

A new Cu(II)-coordination polymer, formulated as {[CuCl(mu(4)-bipna)](NO3)center dot 2.5H(2)O}(n) (1) ((H(2)bipna)Br-2: 1,1'-([1,1 '-biphenyl]-4,4 '-diylbis (methylene))bis (3-carboxypyridin-1-ium) bromide) was synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction technique. The single crystal X-ray diffraction analysis revealed that compound 1 exhibited a 2D -> 2D polycatenane of 3-fold interpenetrated sql layers. The electrochemical performance of 1 was performed both as anode and cathode for Li-ion batteries. In both situations, the capacity values remained around 20-40 mAhg(-1) independent of type of the electrodes. In addition, the thermal and optical properties of compound 1 were investigated.