Unexpected formation of beta, meso-directly linked diporphyrins under Adler-Longo reaction conditions

TEMELLİ B., Kalkan H.

SYNTHETIC COMMUNICATIONS, vol.48, no.16, pp.2112-2117, 2018 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Article
  • Volume: 48 Issue: 16
  • Publication Date: 2018
  • Doi Number: 10.1080/00397911.2018.1486426
  • Journal Name: SYNTHETIC COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Page Numbers: pp.2112-2117
  • Gazi University Affiliated: No

Abstract

Unexpected formation of , meso-directly linked diporphyrin products has been described in the reactions of -formyl porphyrins with pyrrole under Adler-Longo reaction conditions. Preliminary mechanistic studies indicates that -dipyrromethane substituted porphyrin structure is the crucial intermediate for the formation of diporphyrin product. [GRAPHICS] .