Unexpected formation of beta, meso-directly linked diporphyrins under Adler-Longo reaction conditions

TEMELLİ B., Kalkan H.

SYNTHETIC COMMUNICATIONS, cilt.48, sa.16, ss.2112-2117, 2018 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 48 Sayı: 16
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1080/00397911.2018.1486426
  • Dergi Adı: SYNTHETIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Sayfa Sayıları: ss.2112-2117
  • Gazi Üniversitesi Adresli: Hayır

Özet

Unexpected formation of , meso-directly linked diporphyrin products has been described in the reactions of -formyl porphyrins with pyrrole under Adler-Longo reaction conditions. Preliminary mechanistic studies indicates that -dipyrromethane substituted porphyrin structure is the crucial intermediate for the formation of diporphyrin product. [GRAPHICS] .