Agmatine ligand functionalized magnetic alginate beads for removal of U(VI) ions from solution


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BAYRAMOĞLU G., Arica M. Y.

Journal of Radioanalytical and Nuclear Chemistry, 2024 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Publication Date: 2024
  • Doi Number: 10.1007/s10967-024-09548-w
  • Journal Name: Journal of Radioanalytical and Nuclear Chemistry
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Analytical Abstracts, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Food Science & Technology Abstracts, INSPEC, Metadex, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, Civil Engineering Abstracts
  • Keywords: Adsorption, Agmatine ligand, Magnetic alginate beads, Magnetic nanoparticles, U(VI)
  • Gazi University Affiliated: Yes

Abstract

In the presented work, magnetic alginate (MA) beads were prepared and activated with epichlorohydrin and then functionalized with agmatine ligands (MA-A). The materials were analyzed by FTIR, SEM, XRD, and BET methods. The adsorption capacity of the MA-A for U(VI) was 451.4 mg/g. The Langmuir isotherm model well described the experimental data for the adsorption of U(VI) ions. The second-order kinetic model data proposed that the adsorption of U(VI) ions preferred the chemisorption mechanism. The adsorption enthalpy of the MA-A beads for U(VI) ions was 35.4 kJ/mol. After seven cycles of use, the adsorption capacity of MA-A beads was not significantly changed for U(VI) ions. Finally, the functionalization of MA beads with agmatine ligand can be a good candidate for applications for environmental technologies to remove metal ions.