mu(3)-oxo-hexa-mu(2)-pivalato-(pivalic acid-kappa O)-bis(pyridine-kappa N)trimanganese(III,III,II)

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Atıf İçin Kopyala

Sari M., Poyraz M., Buyukgungor O., Cannon R. D.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.62, 2006 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 62
• Basım Tarihi: 2006
• Doi Numarası: 10.1107/s1600536806048343
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
• Gazi Üniversitesi Adresli: Evet

Özet

asymmetric unit of the title compound, [Mn-3(C5H9O2)(6)O(C5H5N)(2)(C5H10O2)], comprises two independent and similar [(Mn2MnO)-Mn-III-O-II{(CH3)(3)CCO2}(6)(py)(2)(CH3)(3)CCOOH] (py = pyridine) molecules each with an Mn-3(mu(3)-O) core. In each molecule, the Mn atoms have octahedral geometry with two coordinated pyridines bonded to two Mn-III and a terminal pivalic acid coordinated to the Mn-II atom.