DETERMINATION OF ORGANOPHOSPHORUS AND TRIAZOLE PESTICIDES BY GAS CHROMATOGRAPHY AND APPLICATION TO VEGETABLE AND COMMERCIAL SAMPLES
JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES, cilt.34, sa.19, ss.2473-2483, 2011 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 34 Sayı: 19
- Basım Tarihi: 2011
- Doi Numarası: 10.1080/10826076.2011.591027
- Dergi Adı: JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.2473-2483
- Gazi Üniversitesi Adresli: Evet
Özet
A multiresidue method using gas chromatography with electron-capture detection (ECD), nitrogen-phosphorus detection (NPD), or flame ionization detection (FID) has been developed for the determination of triazole residues such as triadimefon, penconazole, hexaconazole, diniconazole, and organophosphorus residues such as chlorpyrifos-methyl. The method has been successfully applied to the analysis of tomatoes and eggplant samples. The recoveries obtained from NPD detector for tomatoes and eggplants were in the range 62.0-109% and 66.0-104% with the relative standard deviation varied from 5.0 to 13.1% and 3.2 to 18.0%, respectively. The method was validated and applied for the determination of triazole and organophosphorus pesticides in agrochemical formulations within the recoveries of 96.3-107.2%.