Di-mu-acetato-bis[mu-2-hydroxy-N, N '-bis(2-oxidobenzyl)propane-1,3-diamine]bis(N,N '-dimethylformamide)trinickel(II) N,N '-dimethylformamide disolvate


Sari M., Atakol O., Svoboda I., Fuess H.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.62, 2006 (SCI-Expanded) identifier identifier

Abstract

The title compound, [Ni-3(C17H20N2O2)(2)(C2H3O2)(2)(C3H7-NO)(2)]center dot 2C(3)H(7)NO, is a centrosymmetric trinuclear nickel(II) complex. The central and terminal nickel(II) atoms have distorted octahedral coordination, the central Ni-II atom by six O atoms, and the terminal Ni-II atoms by four O atoms and two N atoms each. The average Ni - O and Ni - N distances for the terminal Ni ions are 2.062 (17) and 2.082 (2) angstrom, respectively. The Ni center dot center dot center dot Ni distance is 3.035 (2) angstrom.