Excellent and convenient procedures for reduction of benzene and its derivatives

Altundas A., Menzek A., Gultekin D., Karakaya M.

TURKISH JOURNAL OF CHEMISTRY, vol.29, no.5, pp.513-518, 2005 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 29 Issue: 5
  • Publication Date: 2005
  • Journal Name: TURKISH JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.513-518
  • Keywords: arenes, lithium, reductions, alcohols, protonations, ethers, METAL-AMMONIA REDUCTION, AROMATIC-COMPOUNDS, ALKALI-METALS, SAFE
  • Gazi University Affiliated: Yes

Abstract

Reductions of benzene, toluene, ortho-xylene, cumene, anisole and benzoic acid to corresponding nonconjugated dienes were realized at room temperature by gas NH3 and Li. The reduced products were easily isolated because THF and dioxane were dissolved in the water. The yields and conversions of the reactions were 70-89% and 80-100%, respectively.