H2 production via H2S decomposition over activated carbon supported Fe- and W- catalysts

DOĞAN M. Y., TAŞDEMİR H. M., ARBAĞ H., YAŞYERLİ N., YAŞYERLİ S.

International Journal of Hydrogen Energy, 2024 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1016/j.ijhydene.2024.02.316
  • Dergi Adı: International Journal of Hydrogen Energy
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Artic & Antarctic Regions, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, Environment Index, INSPEC
  • Anahtar Kelimeler: Activated carbon, Fe, W, H2 production, H2S decomposition
  • Gazi Üniversitesi Adresli: Evet

Özet

This study aims to investigate sawdust-based activated carbon (AC) as catalyst, and as catalyst support for Fe and W in H2 production by H2S decomposition. Activated carbon was prepared with the chemical agent phosphoric acid. The wet impregnation method was used in the preparation of sawdust-based AC supported Fe and W containing catalysts. Commercial mesoporous activated carbon was also used for comparison purposes as catalyst support. N2 adsorption-desorption isotherms of AC showed the presence of both micro/mesoporosity. ICP-OES analyses revealed the phosphorus in the structure of all prepared catalysts. Raman, DTA profiles, and XRD patterns of AC and CMC showed that AC and CMC have amorphous and graphite carbon, respectively. The higher H2S conversion values obtained with AC-supported catalysts compared to CMC-supported catalysts can be attributed to the presence of oxygenated phosphorus in the structure of AC. XPS analysis revealed the presence of WO3 in fresh 10W@AC, and Fe2O3 in fresh 10Fe@AC. After the reaction, XPS analyses showed the formation of WS2 on the 10W@AC catalyst, while it revealed the presence of elemental sulfur and sulfate structures on the 10Fe@AC catalyst. In catalysts containing Fe and W, it is observed that metal-sulfide compounds formed on the surface and in the bulk phase during reaction, as well as phosphorus compounds, may have catalytic activity. H2S conversions over AC and AC-supported catalysts were close to the thermodynamic equilibrium conversion value. To determine the possible product distribution during reaction, the reactor exit stream was analyzed by an online connected FTIR spectrometer. FTIR spectra indicated the formation of CS2, CO, and some CO2 in the reactor exit stream using AC and AC-supported Fe and W catalysts. The activity test results showed that activated carbon prepared by phosphoric acid and activated carbon-supported Fe and W are promising catalysts for H2 production via H2S decomposition.