SYNTHESIS AND SPECTROSCOPIC STUDIES OF METAL(II) TETRACYANONICKELATE COMPLEXES WITH 1,3-THIAZOLIDINE-2-THIONE

KARACAN N., TUFAN Y.

SPECTROSCOPY LETTERS, vol.28, no.5, pp.773-782, 1995 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 28 Issue: 5
  • Publication Date: 1995
  • Doi Number: 10.1080/00387019508009918
  • Journal Name: SPECTROSCOPY LETTERS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.773-782
  • Keywords: IR AND RAMAN SPECTRA, 1,3-THIAZOLIDINE-2-THIONE, HOFMANN-TYPE COMPLEXES, HETEROCYCLIC LIGANDS
  • Gazi University Affiliated: Yes

Abstract

Two new Hofmann-type complexes, M (1,3-thiazolidine-2-thione)(2) Ni(CN)(4) (where M = Ni and Cd), were synthesized and characterized by elemental analysis, magnetic susceptibility data, IR and Raman Spectroscopy. Their structure consist of planar infinite polymeric layers of {M-Ni(CN)(4)}(infinity). 1,3-thiazolidine-2-thione coordinated to Matom above and below this layers is monodentate and S-bonded in these complexes.