An infrared and raman spectroscopic study of pn-T-d-type dl-propylenediaminemetal(II) tetracyanometallate(II) benzene clathrates: M(dl-pn)M '(CN)(4).nC(6)H(6) (M = Mn, M ' = Zn, Cd or Hg; M = Cd, M ' = Cd or Hg; 1 <= n <= 1.5)


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Kantarci Z., Bayrak C., Kasap E.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.33, no.3, pp.285-294, 1999 (SCI-Expanded) identifier identifier

Abstract

IR spectra of Mn(dl-propylenediamine)M(CN)(4).nC(6)H(6) (M = Zn, n = 1.25; M = Cd, n = 1.00 or M = HE, n = 1.18), and IR and Raman spectra of Cd(dl-propylenediamine)M(CN)(4). 1.5C(6)H(6) (M = Cd or Hg) are reported. The spectral data suggest that the former three compounds are similar in structure to the latter two pn-T-d-type clathrates.