Akademik Veri Yönetim Sistemi
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, cilt.84, ss.1004-1020, 2024 (SCI-Expanded)
The adhesion of gases to the electrodes is a major reason for reductions in energy efficiency, and hinders the production of hydrogen in alkaline water electrolysis (AWE). The development of an effective solution to this problem will be crucial for the design and optimization of AWE. In this paper, we present a novel structure for an electrolyser in which baffles are inserted into the channel. The flow process of the electrolyte and the electrochemical reactions in the electrolyser with the new structure are simulated, and the effects of the added baffles on the distribution of the gas phase production and the efficiency of energy conversion are analysed. Several important structural parameters are considered, such as the angle, number and length of the baffles, and corresponding numerical calculations are performed. In order to carry out a comprehensive evaluation of the performance of each electrolyser, the energy efficiency of AWE is evaluated and the current effect, ohmic overvoltage effect and bubble overvoltage effect caused by gas adhesion are quantitatively investigated. The results show that the flow of the electrolyte can be divided into three phases when baffles are added to the channel of the electrolyser, and that the baffles play a crucial role in both the transition phase and the full development phase. The maximum reduction in gas coverage at the electrodes reaches 60% and the maximum increase in energy efficiency reaches more than 3.0% with the addition of baffles. The addition of baffles has significant effects on the current and ohmic overpotential, and the balance between the gas coverage and ohmic overpotential can allow the maximum energy efficiency of the AWE to be achieved.