Crystal structure of bis(isothiocyanato)[2,6-diacetylpyridine bis(4-hydroxybenzoylhydrazone)]Fe(III) Chloride bis(dimethylformamide) solvate


Dilek N., GÜNEŞ B., Buyukgungor O., Gup R.

CRYSTALLOGRAPHY REPORTS, vol.58, no.1, pp.98-101, 2013 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 58 Issue: 1
  • Publication Date: 2013
  • Doi Number: 10.1134/s1063774513010173
  • Journal Name: CRYSTALLOGRAPHY REPORTS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.98-101
  • Gazi University Affiliated: Yes

Abstract

The crystal structure of title compound (Fe[(C25H21N7O4S2)] center dot 4(C3NOH7), where C3NOH7 is dimethylformamide, DMF) was determined by the X-ray diffraction method. This compound crystallizes in the monoclinic C2/c space group, Z = 4. Unit cell parameters are: a = 13.6080(5), b = 17.6375(7), c = 19.5571(6) , beta = 108.753(2)A degrees. The N-H...O and O-H...O interactions stabilize the molecules in the lattice. The structure contains also the solvent dimethylformamide molecules, which are connected with intermoleculer hydrogen bond. The O atoms of DMF molecules take place as acceptor atoms.