Duplex stainless steels are gaining greater interest due to their increasing amounts of application fields. Accordingly, there is a need for awareness of problems associated with improper microstructural distributions such as delta-ferrite (delta-ferrite), austenite and other important intermetallic phases that may form in these steel weldments. Since delta-ferrite versus austenite ratio profoundly influences corrosion and mechanical properties, optimum delta-ferrite ratios must be kept approximately within 35-65 vol % and balance austenite to maintain satisfactory corrosion and mechanical properties on welding of these steels. Cooling rates of welds and alloying elements in base metal are the major factors that determine the final microstructure of these steels. In this work, 3 mm thickness of 2205 duplex stainless-steel plates were TIG (Tungsten Inert Gas) welded with various amounts of nitrogen gas added to argon shielding gas. Specimens were joined within the same welding parameters and cooling conditions. As nitrogen is a potential austenite stabilizer and an interstitial solid solution hardener, the effects of nitrogen on mechanical properties such as hardness profiles, grain sizes and microstructural modifications are investigated thoroughly by changing the welding shielding gas compositions. Increasing the nitrogen content in argon shielding gas also increases the amount of austenitic phase while delta-ferrite ratios decreases. Nitrogen spherodized the grains of austenitic structure much more than observed in delta-ferrite. The strength values of specimens that welded with the addition of nitrogen gas into the argon shielding gas are increased more in both austenitic and delta-ferritic structure as compared to specimens that welded with plain argon shielding gas. The addition of 1 vol % of nitrogen gas into argon shielding gas provided the optimum phase balance of austenite and delta-ferrite in S32205 duplex stainless-steel TIG-welded specimens.