An infrared spectroscopic study on the Hofmann-diam-type 1,12-diaminododecanemetal(II) tetracyanonickelate(II)-aromatic guest clathrates: M(H2N(CH2)(12)NH2)Ni(CN)(4)center dot G(M=Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl)


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Senyel M., Sertbakan T., Kurkcuoglu G., Kasap E., Kantarci Z.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.39, pp.175-180, 2001 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 39
  • Publication Date: 2001
  • Doi Number: 10.1023/a:1008141726024
  • Journal Name: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
  • Page Numbers: pp.175-180
  • Keywords: Hofmann-type clathrates, tetracyanonickelate, 1,12-diaminododecane, infrared spectra, benezene, naphthalene, anthracene, phenanthrene biphenyl, SPECTRA, CO
  • Gazi University Affiliated: Yes

Abstract

Three Hofmann-diaminododecane-type clathrates of the form M(1,12-diaminododecane) Ni(CN)(4).G (M = Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl) have been prepared in powder form. The 1,12-diaminododecane molecules in the host lattice permit the inclusion of bulky guest molecules. The spectral features suggest that these compounds are similar in structure to the other Hofmann-diam-type clathrates.