An infrared spectroscopic study on the Hofmann-diam-type 1,12-diaminododecanemetal(II) tetracyanonickelate(II)-aromatic guest clathrates: M(H2N(CH2)(12)NH2)Ni(CN)(4)center dot G(M=Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl)

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Senyel M., Sertbakan T., Kurkcuoglu G., Kasap E., Kantarci Z.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, cilt.39, ss.175-180, 2001 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 39
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1023/a:1008141726024
  • Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
  • Sayfa Sayıları: ss.175-180
  • Anahtar Kelimeler: Hofmann-type clathrates, tetracyanonickelate, 1,12-diaminododecane, infrared spectra, benezene, naphthalene, anthracene, phenanthrene biphenyl, SPECTRA, CO
  • Gazi Üniversitesi Adresli: Evet

Özet

Three Hofmann-diaminododecane-type clathrates of the form M(1,12-diaminododecane) Ni(CN)(4).G (M = Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl) have been prepared in powder form. The 1,12-diaminododecane molecules in the host lattice permit the inclusion of bulky guest molecules. The spectral features suggest that these compounds are similar in structure to the other Hofmann-diam-type clathrates.