EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, vol.2004, no.5, pp.1143-1148, 2004 (SCI-Expanded)
Article / Article
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Science Citation Index Expanded (SCI-EXPANDED), Scopus
alcohols, bromination, cycloaddition, halogenation, HIGH-TEMPERATURE BROMINATION, 1,3-DIPOLAR CYCLO-ADDITIONS, BENZHOMOBARRELENE DERIVATIVES, REARRANGEMENT REACTIONS, CONTAINING HETEROCYCLES, DOUBLE-BOND, 1,4-EPOXY-1,4-DIHYDRONAPHTHALENE, BEHAVIOR, ADDUCTS, SPECTRA
Gazi University Affiliated:
Cycloaddition reactions of naphthalene-1,4-epoxide (1) with both 7-(methoxycarbonyl)cycloheptatriene (2) and cyclohexadiene (4) give adducts of type 3 and 5 exclusively. Selectivity was observed for the cycloaddition and bromination reactions, but neighboring group participation also occurrs in the latter. The formation of the products is discussed. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.