Cycloaddition reactions of 1,4-dihydronaphthalene-1,4-epoxide with cyclohexadiene and 7-(methoxycarbonyl)cycloheptatriene: Selectivity in additions


Menzek A., Altundas A. , Coruh U., Akbulut N., Lopez E., Hokelek T., ...Daha Fazla

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, cilt.2004, sa.5, ss.1143-1148, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 2004 Konu: 5
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1002/ejoc.200300569
  • Dergi Adı: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  • Sayfa Sayıları: ss.1143-1148

Özet

Cycloaddition reactions of naphthalene-1,4-epoxide (1) with both 7-(methoxycarbonyl)cycloheptatriene (2) and cyclohexadiene (4) give adducts of type 3 and 5 exclusively. Selectivity was observed for the cycloaddition and bromination reactions, but neighboring group participation also occurrs in the latter. The formation of the products is discussed. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.