An infrared spectroscopic study of pyrazine- and 4,4 '-bipyridyl-T-d-type clathrates: Mn (pyrazine) M(CN)(4) benzene (M = Cd or Hg) and Mn (4,4 '-bipyridyl) M(CN)(4). benzene (M = Zn, Cd or Hg)
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.39, pp.115-121, 2001 (Peer-Reviewed Journal)
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JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
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The infrared spectra of the title compounds have been reported. The spectral data suggest that the host framework of these compounds are similar to those of the en-T-d-type clathrate compounds. There is good evidence for hydrogen bonding from ligand molecules to benzene molecules as a pi to sigma hydrogen bond.