Chemical effects in the K alpha and K beta(1,3) of X-ray emission spectra of Fe

Baydas, E.; Oz, ELİF

doi:10.1016/j.elspec.2011.11.003

Chemical effects in the K alpha and K beta(1,3) of X-ray emission spectra of Fe

Atıf İçin Kopyala

Baydas E., Oz E.

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, cilt.185, ss.27-31, 2012 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 185
Basım Tarihi: 2012
Doi Numarası: 10.1016/j.elspec.2011.11.003
Dergi Adı: JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.27-31
Gazi Üniversitesi Adresli: Evet

Özet

Chemical shifts and full widths at half maximum intensity (FWHM) of K alpha and K beta(1,3) X-ray emission lines were measured for the following Fe compounds: Fe, FeCl2, FeCl3 center dot 6H(2)O, FeF2, FeF2 center dot 4H(2)O, FeF3, FeF3 center dot 3H(2)O, FeO3, FeS2, FeSO4. The measurements were performed with a wavelength-dispersive X-ray fluorescence spectrometry (WDXRF). It was found that the calculated results for Fe compounds are strongly correlated with the oxidation state. At the same time chemical effects for halogens compounds are generally more than that other compounds. (C) 2011 Elsevier B.V. All rights reserved.