Chemical effects in the K alpha and K beta(1,3) of X-ray emission spectra of Fe
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, cilt.185, ss.27-31, 2012 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 185
- Basım Tarihi: 2012
- Doi Numarası: 10.1016/j.elspec.2011.11.003
- Dergi Adı: JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.27-31
- Gazi Üniversitesi Adresli: Evet
Özet
Chemical shifts and full widths at half maximum intensity (FWHM) of K alpha and K beta(1,3) X-ray emission lines were measured for the following Fe compounds: Fe, FeCl2, FeCl3 center dot 6H(2)O, FeF2, FeF2 center dot 4H(2)O, FeF3, FeF3 center dot 3H(2)O, FeO3, FeS2, FeSO4. The measurements were performed with a wavelength-dispersive X-ray fluorescence spectrometry (WDXRF). It was found that the calculated results for Fe compounds are strongly correlated with the oxidation state. At the same time chemical effects for halogens compounds are generally more than that other compounds. (C) 2011 Elsevier B.V. All rights reserved.