Vibrational spectroscopic study of [1,2-bis(4-pyridyl)ethane]metal(II) tetracyanonickelate(II). 2 m-xylene clathrates


Tufan Y., Karacan N., OzdemIr Ü.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.40, no.4, pp.275-278, 2001 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 40 Issue: 4
  • Publication Date: 2001
  • Doi Number: 10.1023/a:1012735828435
  • Journal Name: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.275-278
  • Keywords: Hofmann-type clathrate, 1,2-bis(4-pyridyl)ethane, m-xylene inclusion compounds, IR and Raman Spectra

Abstract

Four new Hofmann-type clathrates of the form M(bpa)(2)Ni(CN)(4). 2m-xylene (M = Mn , Fe , Co and Ni; bpa = 1,2-bis(4-pyridyl)ethane) have been synthesized and characterized by vibrational spectroscopy. The M(bpa)(2)Ni(CN)(4) (M = Fe and Co) host structure is similar to the classical Hofmann-type host framework composed of layers of a two dimensional catena-metal tetra-mu -cyanonickelate(II) network, but in M(bpa)(2)Ni(CN)(4) (M = Mn and Ni), the Ni(CN)(4) moiety behaves as a bidentate -[NC-Ni(CN)(2)-CN-]- unit in the host framework.