Vibrational spectroscopic study of [1,2-bis(4-pyridyl)ethane]metal(II) tetracyanonickelate(II). 2 m-xylene clathrates

Tufan Y., Karacan N., OzdemIr Ü.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, cilt.40, sa.4, ss.275-278, 2001 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 40 Sayı: 4
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1023/a:1012735828435
  • Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.275-278
  • Anahtar Kelimeler: Hofmann-type clathrate, 1,2-bis(4-pyridyl)ethane, m-xylene inclusion compounds, IR and Raman Spectra
  • Gazi Üniversitesi Adresli: Evet

Özet

Four new Hofmann-type clathrates of the form M(bpa)(2)Ni(CN)(4). 2m-xylene (M = Mn , Fe , Co and Ni; bpa = 1,2-bis(4-pyridyl)ethane) have been synthesized and characterized by vibrational spectroscopy. The M(bpa)(2)Ni(CN)(4) (M = Fe and Co) host structure is similar to the classical Hofmann-type host framework composed of layers of a two dimensional catena-metal tetra-mu -cyanonickelate(II) network, but in M(bpa)(2)Ni(CN)(4) (M = Mn and Ni), the Ni(CN)(4) moiety behaves as a bidentate -[NC-Ni(CN)(2)-CN-]- unit in the host framework.