{Bis(N,N-dimethylformamide)[mu-N,N '-bis(salicylidene)-1,3-propane-diaminato]nickel(II)}dibromozinc(II)


Arici C., Svoboda I., Sari M., Atakol O., Fuess H.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.57, ss.31-32, 2001 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Cilt numarası: 57
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1107/s0108270100014487
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Sayfa Sayıları: ss.31-32

Özet

The title compound, [NiZnBr2(C3H7NO)(2)(C17H16N2O2)], is a heterodinuclear nickel complex. The Ni atom has an irregular octahedral environment involving two O and two N atoms from the bis(salicylidene)-1,3-propanediaminate ligand in the equatorial plane, and two O atoms from the dimethylformamide groups. The Zn-O-Ni, O-Zn-O, Ni-O-Zn and O-Ni-O angles in the bridged plane are 100.1 (2), 79.9 (2), 100.4 (2) and 78.89 (17)degrees, respectively. The Ni . . . Zn distance is 3.0738 (19) Angstrom.