Crystal structure of catena-poly[[bis(acetato-kappa O)-copper(II)]-bis[mu-4-(1H-imidazol-1-yl)phenol]kappa N-2(3):O;kappa(2) O:N-3]

POYRAZ, MEHMET; SARI, MUSA

doi:10.1107/s2056989017000780

Crystal structure of catena-poly[[bis(acetato-kappa O)-copper(II)]-bis[mu-4-(1H-imidazol-1-yl)phenol]kappa N-2(3):O;kappa(2) O:N-3]

Atıf İçin Kopyala

POYRAZ M., SARI M.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.73, ss.209-217, 2017 (ESCI)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 73
Basım Tarihi: 2017
Doi Numarası: 10.1107/s2056989017000780
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
Sayfa Sayıları: ss.209-217
Gazi Üniversitesi Adresli: Evet

Özet

In the title compound, [Cu(CH3COO)(2)(C9H8N2O)(2)] n, the Cu II ion resides on a centre of inversion, displaying a tetragonally distorted octahedral coordination environment defined by two pairs of N and O atoms of symmetry-related 4-(1H-imidazol-1-yl)phenol ligands and the O atoms of two symmetry-related acetate ligands. The bridging mode of the 4-(1H-imidazol-1-yl) phenol ligands is associated with a very long Cu center dot center dot center dot O interactions involving the phenol O atom of the heterocyclic ligand, which creates chains extending parallel to [100]. In the crystal, the chains are arranged in a distorted hexagonal rod packing and are linked via C-H center dot center dot center dot O hydrogen bonds and by pi-pi stacking interactions involving centrosymmetrically related pairs of imidazole and phenol rings.