Syntheses, structural and antimicrobial studies of polymeric 3D Co(II) and 1D Cu(II) complexes of 4,4′-ethylenedipyridine with 2,5-pyridinedicarboxylic acid
Polyhedron, cilt.299, 2026 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 299
- Basım Tarihi: 2026
- Doi Numarası: 10.1016/j.poly.2026.118377
- Dergi Adı: Polyhedron
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica, Compendex, Academic Search Ultimate (EBSCO), Engineering Source (EBSCO)
- Anahtar Kelimeler: 2,5-pyridinedicarboxylic acid, 4,4′-Ethylenedipyridine, antimicrobial activity, polymeric complex
- Gazi Üniversitesi Adresli: Evet
Özet
3D Co(II) {[(dpc)Co(dpc)Co(edp)1/2]}n, 1} and 1D Cu(II) {{[Cu(edp)(H2O)][Cu(dpc)2]}n, 2} novel polymeric complexes were synthesized form 2,5-pyridinedicarboxylic acid (H2dpc) and 4,4′-ethylenedipyridine (edp). The structures of complexes 1 and 2 were characterized by single-crystal X-ray diffraction analysis, elemental analysis, AAS, FTIR, UV–Vis, and magnetic susceptibility measurements. Complexes 1 and 2 have polymeric structures and crystallographic inversion centers in their symmetric units. The metal atoms exhibit a trigonal bipyramidal and octahedral geometry in complex 1, and a distorted square-pyramidal and T-shaped geometry in complex 2. A comprehensive examination was conducted on the antimicrobial susceptibility of all compounds against C. albicans (yeast), S. aureus, P. aeruginosa, E. coli, E. faecalis, L. monocytogenes, and B. subtilis (bacteria). The antimicrobial activities were contrasted with those of Fluconazole, Ketoconazole, Levofloxacin, Vancomycin, Chloramphenicol, and Cefepime.