Investigation of the solid-state conductivity and the potentiometric stability constant relationships of new amino acid-Schiff bases and their complexes


Sari N., Gurkan P.

TRANSITION METAL CHEMISTRY, cilt.28, sa.6, ss.687-693, 2003 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 28 Konu: 6
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1023/a:1025465621449
  • Dergi Adı: TRANSITION METAL CHEMISTRY
  • Sayfa Sayıları: ss.687-693

Özet

Cu-II, Ni-II and Co-II complexes of new tridentate amino acid-Schiff bases derived from furfural and DL-alanine, DL-valine and DL-phenylalanine were prepared and characterized by analytical, spectroscopic, (i.r., u.v.-vis., H-1-n.m.r and C-13-n.m.r) techniques, molar conductivity, magnetic and thermal measurements. Protonation constants of the Schiff bases and stability constants of the complexes have been determined potentiometrically in water. Solid-state conductivities of the synthesized substances were measured using the four-probe technique on a compressed pellet at room temperature.