© 2021, King Fahd University of Petroleum & Minerals.Studies on the usage of gasoline–alcohol blends as an alternative fuel in spark-ignition engines have recently gained momentum. In the present research, energy, exergy, environmental, enviroeconomic, exergoenvironmental, and exergoenviroeconomic analyses were conducted with the performance and emission values acquired by utilizing gasoline, gasoline–heptanol, and gasoline–hexanol fuels (G100, HEX5-20, and HP5-20) as a fuel under different powers at a constant speed of 1600 rpm in a single-cylinder four-stroke spark-ignition engine. As the ratio of alcohol in fuel blends increases, fuel consumption also increases. NOX emission is higher, and CO and HC emissions are lower in alcohol-based fuel blends than G100 fuel. The highest thermal efficiency is 41.09% in G100 fuel at a power of 5 kW. As the ratio of alcohol in fuel blends increases, thermal efficiency decreases. The highest exergy destruction and entropy generation were determined to be 6.25 kW and 0.02134 kW/K, respectively, in HP20 fuel at a power of 5 kW. Entropy generation increases with an increase in the ratio of alcohol in alcohol-based fuels. HEX20 and HP20 fuels produce 25% and 30% more entropy, respectively, compared to G100 fuel. The mass and financial costs of the damage caused by the CO2 emission of fuels to the environment were determined by conducting four different analyses using energy and exergy analysis data. According to the exergoenvironmental and exergoenviroeconomic analyses, HP20 fuel reached the highest environmental pollution values of 4538.19 kg CO2/month and 65.804 $/month, respectively. The environmental cost of the CO2 emission released from the exhaust to the atmosphere is higher in alcohol-based fuels than G100 fuel. As a result of all analyses, it was concluded that hexanol and heptanol could be alternative fuels in spark-ignition engines under particular conditions.