Vibrational spectroscopic studies on the tn-Td-type Mn(tn)Zn(CN)(4)center dot 2C(6)H(6) and the chelated tn-Td-type Zn(tn)Zn(CN)(4)center dot 2C(6)H(6) clathrates


Kantarci Z., Bayrak C.

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, cilt.30, sa.1, ss.59-68, 1998 (SCI-Expanded) identifier identifier

Özet

IR spectra of Mn(trimethylenediamine)Zn(CN)(4) . 2C(6)H(6) and IR and Raman spectra of Zn(trimethylenediamine)Zn(CN)(4) . 2C(6)H(6) are reported. The spectral data suggest that the host frameworks of these compounds are similar to those of the m-Td-type Cd(trimethylenediamine)M(CN)(4) . 2benzene (M = Cd or Hg) and the chelated pn-Td-type Cd(propylenediamine)Cd(CN)(4) . 1,2-dichloroethane clathrates, respectively.