NO reduction by urea under lean conditions over single-step sol-gel Cu/alumina catalyst


Seker E., Yasyerli N. , Gulari E., Lambert C., Hammerle R.

JOURNAL OF CATALYSIS, vol.208, no.1, pp.15-20, 2002 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 208 Issue: 1
  • Publication Date: 2002
  • Doi Number: 10.1006/jcat.2002.3572
  • Title of Journal : JOURNAL OF CATALYSIS
  • Page Numbers: pp.15-20

Abstract

We present the catalytic activity of 1% Cu on alumina catalyst prepared using a single-step sol-gel process (designated 1% Cu-SG) as a function of oxygen, water, and SO2 in the feed for the reduction of NO with an aqueous urea solution. Our results show that NO, conversion activity of 1% Cu-SG is dependent on oxygen in the feed. The maximum conversion increased from 91 to 99% when the amount of oxygen in the feed was changed from 2 to 14%. Also, the location of maximum conversion temperature decreased from 400 to 377degreesC. Short-term and long-term exposure of the catalyst to a gas mixture containing 25 PPM SO2 did not result in activity loss at any temperature as long as aqueous urea was present in the feed. However, temporary interruption of aqueous urea solution resulted in permanent activity loss. Our attempt to reactivate the catalyst with propene failed to recover the original activity. (C) 2002 Elsevier Science (USA).