Synthesis of novel C-2 substituted imidazoline derivatives having the norbornene/dibenzobarrelene skeletons


ÇAPAN İ., SERVİ S.

ARKIVOC, ss.131-142, 2018 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2018
  • Doi Numarası: 10.24820/ark.5550190.p010.654
  • Dergi Adı: ARKIVOC
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.131-142
  • Anahtar Kelimeler: Cycloadditions, imidazoline, norbornene, dibenzobarrelene, guanidine, amide, ONE-POT SYNTHESIS, FACILE SYNTHESIS, 2-IMIDAZOLINES, BENZIMIDAZOLES, CATALYST, SCAFFOLD, DESIGN, SYSTEM
  • Gazi Üniversitesi Adresli: Evet

Özet

Novel imidazoline derivatives were synthesized from the norbornene and dibenzobarrelene skeletons which were obtained by the Diels-Alder reactions of anthracene and cyclopentadiene with the different dienophiles, such as fumaronitrile and fumaric acid. Synthesis of the C-2 substituted imidazolines was performed with high yields from various dinitriles and diacyl dichlorides.