3,5-Dimethylpyrazolium Chlorochromate(VI): An Efficient Reagent for Solvent-Free Oxidation of Organic Substrates


Canbulat M., Ozgun B.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, vol.42, no.5, pp.634-637, 2012 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 42 Issue: 5
  • Publication Date: 2012
  • Doi Number: 10.1080/15533174.2011.614990
  • Title of Journal : SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Page Numbers: pp.634-637

Abstract

A new chromium(VI) reagent 3,5-dimethylpyrazolium chlorochromate, C5H8N2H[CrO3Cl] (DmpzHCC), was synthesized and used for the selective oxidation of various organic compounds under solvent-free conditions with high efficiency. This new compound has certain advantages over its companion analogues in terms of controlled acidity, amount of oxidant, lack of solvent, short reaction times, and high yields.