Pore structure and surface acidity evaluation of Fe-PILCs

Balci S., Gokcay E.

TURKISH JOURNAL OF CHEMISTRY, vol.33, no.6, pp.843-856, 2009 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 33 Issue: 6
  • Publication Date: 2009
  • Doi Number: 10.3906/kim-0807-17
  • Journal Indexes: Science Citation Index Expanded, Scopus, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.843-856


Fe-PILCs via different conditions using smectites from Hancili (Turkey) and Wyoming (USA) were synthesised. Presaturation had little effects on the basal spacing values while it had important effects on thermal stabilities of the products. Products having basal spacing (d(001)) around 1.30 nm and surface area up to 160 m(2) g(-1) were obtained. The thermal behaviour, X-ray diffraction (XRD) patterns, and nitrogen adsorption/desorption experiments confirmed that thermally stable and micro-mesoporous products were obtained although at elevated calcination temperature. Delaminated sample with basal spacing value of 2.79 nm was obtained. Surface acidity of clay was enhanced by pillaring. Chemically sorbed pyridine Fourier transform infrared spectroscopy (FTIR) bands were preserved at elevated desorption temperatures.