Novel Poly(Styrene) Attached Schiff Bases for Uptake Mn(II) and Ni(II) Ions and as Antimicrobial Agent against Micrococcus luteus


Nartop D., Sari N.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, vol.22, no.4, pp.772-779, 2012 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 22 Issue: 4
  • Publication Date: 2012
  • Doi Number: 10.1007/s10904-011-9634-z
  • Journal Name: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.772-779
  • Keywords: Polymer-bound Schiff bases, (Aminomethyl)polystyrene, Antimicrobial activities, Selectivity, COMPLEXES, SELECTIVITY, OXIDATION, POLYMERS
  • Gazi University Affiliated: Yes

Abstract

In this study, three novel poly(styrene) attached Schiff bases (AMP-SB) were synthesized from condensation reaction of (aminomethyl)polystyrene with 2-hydroxy-5-bromobenzaldehyde, 2-hydroxy-5-methylbenzaldehyde and 2-hydroxy-5-chlorobenzaldehyde for uptake from solutions containing Mn(II) and Ni(II) ions and as antimicrobial agent against Micrococcus luteus. Furthermore coordination polymers were synthesized including Mn(II) and Ni(II) ions for understand to geometric structure of uptake ions. Polymers attached Schiff bases and coordination polymers were characterized by means of elemental analyses, magnetic measurements, FTIR, UV-GB, TG/DTA and H-1-NMR. The Ni(II) and Mn(II) contents in the metal-containing polymer complexes were determined by the ICP-MS technique. Antibacterial activities of the polymers attached Schiff bases and their complexes were studied by the well-diffusion method against M. luteus (ATCC-9341).