KINETICS AND MECHANISM OF THE OXIDATION OF BENZYL ALCOHOL BY POTASSIUM CHLOROCHROMATE


OZGUN B., PEK A.

REACTION KINETICS AND CATALYSIS LETTERS, cilt.43, sa.2, ss.589-594, 1991 (SCI-Expanded, Scopus)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 43 Sayı: 2
  • Basım Tarihi: 1991
  • Doi Numarası: 10.1007/bf02064733
  • Dergi Adı: REACTION KINETICS AND CATALYSIS LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.589-594
  • Gazi Üniversitesi Adresli: Hayır

Özet

The kinetics of the oxidation of benzyl alcohol by potassium chlorochromate, KCrClO3, has been studied in dimethyl sulfoxide-dichloromethane medium. The reaction is catalyzed by acid. The effects of temperature and solvent composition were studied and activation parameters evaluated. Probable mechanisms are discussed.