Surface chemical conversion of 3-glycidoxypropyldimethylethoxysilane on hydroxylated silicon surface: FT-IR, contact angle and ellipsometry analysis


DEMİRCİ S., Kinali-Demirci S., ÇAYKARA T.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.99, ss.144-149, 2012 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 99
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1016/j.saa.2012.08.090
  • Dergi Adı: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Sayfa Sayıları: ss.144-149

Özet

The chemical conversion of the top surface of 3-glycidoxypropyldimethylethoxysilane (GPDMES) on hyroxylated silicon surface has been studied as a function of reaction time. A multiple-step procedure was applied in this study. At first, GPDMES molecules were self-assembled on the hydroxylated silicon surface. The second step was the modification of epoxy groups with 3,3'-iminodipropionitrile and the last step was the amidoximation reaction of nitrile groups. Existence of the monolayers covalently attached to silicon surfaces were revealed by X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy (FT-IR). Modification, conversion and thickness of surfaces were followed by FT-IR and ellipsometry analysis. (C) 2012 Elsevier B.V. All rights reserved.