Synthesis, Crystal Structure, and Spectroscopic Studies of N-(4-Bromobenzylidene)-N '-(2-Pyridyl) Hydrazine Schiff Base Molecule

TUNÇ T., Tezcan H., ŞAHİN E., Dilek N.

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, cilt.552, ss.194-208, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 552
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1080/15421406.2011.591702
  • Dergi Adı: MOLECULAR CRYSTALS AND LIQUID CRYSTALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.194-208
  • Anahtar Kelimeler: Condensation reaction, crystal structure, hydrazone, Schiff base, X-ray diffraction, X-RAY-STRUCTURE, COMPLEXES, COPPER(II), BEHAVIOR
  • Gazi Üniversitesi Adresli: Evet

Özet

A new Schiff base complex N-(4-bromobenzylidene)-N'-(2-pyridyl) hydrazine, C12H10N3Br, has been synthesized and characterized by elemental analyses, mass, H-1 NMR, ultraviolet-visible (UV-VIS), and IR spectroscopy and single-crystal X-ray determination. The p-Br-benzene and pyridine rings are almost planar and the dihedral angle between the planes is 11.1(3)degrees. The crystal structure is stabilized by intermolecular N-H center dot center dot center dot N-Py hydrogen bonding interaction. X-ray diffraction analyses show that N-(4-bromobenzylidene)-N'-(2-pyridyl) hydrazine Schiff base molecule crystallizes in the monoclinic system, P2(1)/c space group, a = 5.611(5) angstrom, b = 19.566(5) angstrom, c = 10.715(5) angstrom, beta = 98.766(5)degrees, and V = 1162.60(12) angstrom(3).