A BIDESMOSIDIC HEDERAGENIN HEXASACCHARIDE FROM THE ROOTS OF SYMPHYTUM-OFFICINALE

MOHAMMAD F., NOORWALA M., AHMAD V., SENER B.

PHYTOCHEMISTRY, cilt.40, sa.1, ss.213-218, 1995 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 40 Sayı: 1
  • Basım Tarihi: 1995
  • Doi Numarası: 10.1016/0031-9422(95)00246-4
  • Dergi Adı: PHYTOCHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.213-218
  • Anahtar Kelimeler: SYMPHYTUM OFFICINALE, BORAGINACEAE, ROOTS, TRITERPENOID SAPONIN, SYMPHYTOXIDE B, HEDERAGENIN, TRITERPENOID SAPONINS, STRUCTURE ELUCIDATION, GUAIACUM-OFFICINALE, GLYCOSIDES, SPECTRA
  • Gazi Üniversitesi Adresli: Hayır

Özet

A new bidesmosidic triterpenoidal saponin 3-O-[beta-D-glucopyranosyl-(1 --> 4)-beta-D-glucopyranosyl-(1 --> 4)-alpha-L-arabinopyranosyl]-hederagenin-28-O-[alpha-L-rhamnopyranosyl-(1 --> 4)-beta-D-glucopyranosyl-(1 --> 6)-beta-D-glucopyranosyl] ester, was isolated from the roots of Symphytum of officinale. The structure was assigned by chemical methods and spectral analysis (H-1, C-13, DEFT, NMR, EI-MS and FAB-MS) including H-1-H-1 COSY, H-1-C-13 COSY and HOHAHA. The prosapogenin of this saponin is also a new compound.