Structural features of dibromobis(nicotinamide)zinc(II) complex


Sahin E., İDE S., Atac A., Yurdakul Ş.

JOURNAL OF MOLECULAR STRUCTURE, vol.616, pp.253-258, 2002 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 616
  • Publication Date: 2002
  • Doi Number: 10.1016/s0022-2860(02)00346-0
  • Title of Journal : JOURNAL OF MOLECULAR STRUCTURE
  • Page Numbers: pp.253-258

Abstract

A novel ligand complex of Zn(II) with nicotinamide (one form of niacine) and two bromine ions were synthesised and characterised on the basis of elemental analysis, FT-IR spectroscopy and X-ray crystallography. Crystal system is monoclinic, space group C2/c (no: 15), cell parameters are a = 13.3535(9) Angstrom, b = 6.3859(7) Angstrom, c = 19.1940(19) Angstrom, beta = 101.75(3)degrees, V = 1602.5(3) Angstrom(3) and Z = 4. It has been proven that the nicotinamide ligands in the structure of the Zn(H) complex are coordinated to the metal ion with N atoms ([ZnBr2(na)(2)] where na: nicotinamide). (C) 2002 Elsevier Science B.V. All rights reserved.