Highly Porous Poly(o-Phenylenediamine) Loaded Magnetic Carboxymethyl Cellulose Hybrid Beads for Removal of Two Model Textile Dyes

Arica T. A., Balci F. M., Balci S., ARICA M.

FIBERS AND POLYMERS, cilt.23, sa.10, ss.2838-2854, 2022 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 23 Sayı: 10
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1007/s12221-022-0221-4
  • Dergi Adı: FIBERS AND POLYMERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Aerospace Database, Compendex, INSPEC, Metadex
  • Sayfa Sayıları: ss.2838-2854
  • Anahtar Kelimeler: Adsorption, Carboxymethyl cellulose, Textile dye removal, Magnetic, Poly(o-phenylenediamine), METHYLENE-BLUE, CONGO RED, COMPOSITE, ADSORBENT, ADSORPTION, ISOTHERMS, KINETICS, SORPTION, POLYETHYLENIMINE, HYDROGEL
  • Gazi Üniversitesi Adresli: Evet

Özet

Ensuring the removal of complex dyes from wastewater is a topic of great interest as it is vital for the environment. The present study reports a facile preparation method for poly(o-phenylenediamine) [p(o-PDA)] micro-particles loaded to magnetic carboxymethyl cellulose (CMC) hydrogel beads as adsorbents. The prepared products were characterized by FTIR, TGA, VSM, SEM, BET, and zeta sizer. The Fe3O4@p(o-PDA)@CMC beads were used for the removal of Reactive Blue 4 (RB-4) and Congo Red (CR) textile dyes from an aqueous medium. Different factors, such as adsorbent dose, initial pH, ionic strength, contact time, temperatures, and initial RB-4 and CR concentrations were examined. The maximum adsorption capacities of the RB-4 dye and CR at optimum pH 5 reached 398.7 and 524.6 mg/g in 120 min, respectively. The adsorption of RB-4 and CR on the hybrid magnetic beads can be due to the electrostatic, hydrogen bonding, and pi-pi interactions. Moreover, the magnetic hybrid beads showed easy regeneration ability and good reusability. The adsorbent can be a very good candidate for the efficient removal of micro-pollutant from wastewater.