Elucidation of the mechanism of an aromatic substitution reaction by the utilization of micelles as mechanistic probes

Tascioglu, S; Gurdere, MB

doi:10.1016/s0927-7757(00)00575-6

Elucidation of the mechanism of an aromatic substitution reaction by the utilization of micelles as mechanistic probes

Atıf İçin Kopyala

Tascioglu S., Gurdere M.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, cilt.173, ss.101-107, 2000 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 173
Basım Tarihi: 2000
Doi Numarası: 10.1016/s0927-7757(00)00575-6
Dergi Adı: COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.101-107
Gazi Üniversitesi Adresli: Hayır

Özet

A mechanistic study has been performed in order to elucidate the mechanism of the iodination of aniline and the iodination species in this reaction. For this purpose, the reaction has been performed in the presence of cationic and anionic surfactants in order to utilize from micellar charge effect. The results of this study provided evidence to support the hyphothesis that the iodination reagent in this reaction is hypoiodous acid. (C) 2000 Elsevier Science B.V. All rights reserved.