Infrared spectroscopic study on the Hofmann-dadn-type and the T-d-dahxn-type clathrates

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Ozbay A., Saglam S., Sertbakan T. R., Kasap E., Ozcelik S.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, cilt.58, sa.1-2, ss.49-54, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 58 Sayı: 1-2
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1007/s10847-006-9109-y
  • Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
  • Sayfa Sayıları: ss.49-54
  • Anahtar Kelimeler: clathrates, infrared spectroscopy, 1,10-diaminodecane, 1,6-diaminohexane, VIBRATIONAL-SPECTRA, CRYSTAL-STRUCTURES, DISUBSTITUTED COMPOUNDS, BENZENE DERIVATIVES, INCLUSION-COMPOUNDS, CD, M=MN, HG, CO, COMPLEXES
  • Gazi Üniversitesi Adresli: Evet

Özet

Infrared spectra of M(1,10-diaminodecane)Ni(CN)(4)center dot,1,5 G ( M=Co, Ni or Cd; G=o-xylene, m-xylene, p-xylene) and Cd(1,6-diaminohexane)M(CN)(4)center dot C6H6 ( M=Cd or Hg) clathrates are reported. The 1,10-diaminodecane and 1,6-diaminohexane molecules in the host permit the inclusion of bulky guest molecules. The spectral data of clathrates were compared with those of the corresponding host. The spectral features suggest that these compounds are similar in structure to other Hofmann-type and Hofmann-T-d type clathrates, respectively.