Synthesis of novel aza-heterocyclic derivatives from diester and diacid chlorides having the dibenzobarrelene skeleton


ÇAPAN İ. , SERVİ S.

SYNTHETIC COMMUNICATIONS, cilt.48, sa.10, ss.1164-1171, 2018 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 48 Konu: 10
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1080/00397911.2018.1437449
  • Dergi Adı: SYNTHETIC COMMUNICATIONS
  • Sayfa Sayıları: ss.1164-1171

Özet

When attempting to synthesize the symmetric aza-heterocyclic-substituted dibenzobarrelene derivatives from the 2-aminobenzimidazole (or 2-aminoimidazoline) with diacid chlorides and diester in the presence of various organic bases, different products were isolated in high yield. NMR spectroscopic analysis proved these products to be dibenzobarrelene-substituted fused benzimidazodiazepine, imidazolinediazepine, and dicarboxamides derivatives. Cyclic or noncyclic dicarboxamides with the dibenzobarrelene skeleton have been synthesized for the first time using these methods.