Vibrational spectroscopic investigations of M(imidazole)(2) Ni(CN)(4) center dot 2C(6)H(12) clathrates

Tufan Y., Karacan N., Davies J.

VIBRATIONAL SPECTROSCOPY, vol.23, no.1, pp.51-55, 2000 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 23 Issue: 1
  • Publication Date: 2000
  • Doi Number: 10.1016/s0924-2031(99)00074-0
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.51-55
  • Keywords: Hofmann-type clathrate, metal-imidazole complexes, cyclohexane inclusion compounds, IR and Raman spectra, INFRARED-SPECTRA, IMIDAZOLE
  • Gazi University Affiliated: Yes


Four new clathrates of the formula M(Imidazole)(2)Ni(CN)(4). 2C(6)H(12) (M is Mn, Co, Ni and Cd) have been prepared and their infrared and the Raman spectrum of Cd clathrate are reported. The spectral results suggest that these compounds belong to the Hofmann-type clathrates. (C) 2000 Elsevier Science B.V. All rights reserved.