Redetermination of the mixed-valence hexa-nuclear manganese oxide complex di-mu(4)-oxo-tetra-mu(3)-pivalato-hexa-mu(2)-pivalato-tetrakis(pivalic acid)dimanganese(III)tetra-manganese(II) at 100 K


Poyraz M., Sari M., Cevik S., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.62, 2006 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 62
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1107/s1600536806019155
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Özet

The structure of the title compound, [Mn-6(C4H9O2)(10)O-2(C4H10O2)(4)], has been redetermined at 100 K. The improved precision of the structure determination allowed the determination of the positions of the Mn-III atoms in the Mn6O2 core. The Mn(III)cMn(III) distance of 2.744 (3) angstrom is significantly shorter than the remaining Mn(II)cMn(III) distances [3.106 (3)-3.137 (3) angstrom].