Synthesis and characterization a new 2D mixed valence CuI/CuII polymer complex of 4,4′-ethylenedipyridine and 2,6-pyridinedicarboxylic acid
Journal of the Indian Chemical Society, cilt.103, sa.8, 2026 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 103 Sayı: 8
- Basım Tarihi: 2026
- Doi Numarası: 10.1016/j.jics.2026.102721
- Dergi Adı: Journal of the Indian Chemical Society
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, EMBASE
- Anahtar Kelimeler: 2,6-pyridinedicarboxylic acid, 4,4′-Ethylenedipyridine, CuI/II complex, Octahedral geometry, T-shaped geometry
- Gazi Üniversitesi Adresli: Evet
Özet
A novel 2D mixed valence polymeric CuI/CuII complex {[(edp)CuI[CuII(dpc)2]CuI(edp)].7H2O}n (1) of 2,6-pyridinedicarboxylic acid (H2dpc) and 4,4′-ethylenedipyridine (edp) was obtained and characterized by X-ray crystallographic, elemental analysis, atomic absorption spectroscopy (AAS), FTIR, UV-Visible spectroscopy, magnetic moment, and molar conductive analyses. The complex crystallized in the P-1 space group in the triclinic crystal system. The structure of 1 contains one CuII) (Cu1) and two CuI (Cu2, and Cu3) cations, two dpc2− anions as a bridge, two edp, and seven uncoordinated water molecules. While Cu1 has an distorted octahedral geometry, Cu2 and Cu3 have a T-shaped geometry. The Cu2 and Cu3 atoms on both edp's have symmetry centers, and the structure has formed a polymer chain via the symmetric atoms.